To call Future methods from Process Builder, call the future method from the in-vocable method. Check the below code for reference.
Sample Code:
public class LightningProcessBuilder {
@InvocableMethod
public static void sendEmailToOwner( List < String > listUserNames ) {
callEmailSend( listUserNames );
}
@future
public static void callEmailSend( List < String > listUserNames ) {
//Write the logic.
//If it is a call out, use callout = true in future annoation
}
}